You can iterate through each and every node and see if a node exists.
doc.Load(xmlPath);
XmlNodeList node = doc.SelectNodes("//Nodes/Node");
foreach (XmlNode chNode in node)
{
try{
if (chNode["innerNode"]==null)
return true; //node exists
//if ... check for any other nodes you need to
}catch(Exception e){return false; //some node doesn't exists.}
}
You iterate through every Node elements under Nodes (say this is root) and check to see if node named 'innerNode' (add others if you need) exists. try..catch is because I suspect this will throw popular 'object reference not set' error if the node does not exist.