Format with Currency format string
=Format(Fields!Price.Value, "C")
It will give you 2 decimal places with "$" prefixed.
You can find other format strings on MSDN: Adding Style and Formatting to a ReportViewer Report
Note: The MSDN article has been archived to the "VS2005_General" document, which is no longer directly accessible online. Here is the excerpt of the formatting strings referenced:
Formatting Numbers
The following table lists common .NET Framework number formatting
strings.
Format string, Name
C or c Currency
D or d Decimal
E or e Scientific
F or f Fixed-point
G or g General
N or n Number
P or p Percentage
R or r Round-trip
X or x Hexadecimal
You can modify many of the format strings to include a precision
specifier that defines the number of digits to the right of the
decimal point. For example, a formatting string of D0 formats the
number so that it has no digits after the decimal point. You
can also use custom formatting strings, for example, #,###.
Formatting Dates
The following table lists common .NET Framework date formatting
strings.
Format string, Name
d Short date
D Long date
t Short time
T Long time
f Full date/time (short time)
F Full date/time (long time)
g General date/time (short time)
G General date/time (long time)
M or m Month day
R or r RFC1123 pattern
Y or y Year month
You can also a use custom formatting strings; for example, dd/MM/yy.
For more information about .NET Framework
formatting strings, see Formatting Types.